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Chemistry
Natural science concerned with description and classificaton of matter, changes matter undergoes, and energy associated with each
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Divisions of Chemistry
- Inorganic (Genderal)
- Organic
- Bichemistry
- Embalming chemistry
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Inorganic (General) chemistry
Studies properties and reactions of elements, excluding organic or certain carbon-containing compounds
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Organic chemistry
Study of Carbon and its compounds
More carbon compounds than non-carbon compounds
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Biochemistry
Chemistry dealing with compounds produced by living organisms
Subdivision of organic chemistry
Reffered to as physiological chemistry or chemistry of plant and animal systems
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Embalming chemistry
Study of chemical post-mortem (decompostion) changes, composition of embalming fluids, interactions between each
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Chemical measurements - Metric system
- Length - meter
- Volume - liter
- Mass - Kilogram
- Heat- calorie
- Temperature - Kelvin
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Length - meter
Fundamental unit
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Volume - liter
derived unit, 1 L = 1.06 qt.
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Mass - kilogram
Fundamental unit, measure of amount of matter it contains, remails constant regardless of location
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Heat - calorie (small c)
Amount of hear required to raise temp. of 1 gram of water
large Calorie or Kilo-calorie (Cal or Kg-cal) amount of heat required to raise temp. of one kilogram of water one degree Celsius
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Temperature - Kelvin (K)
Standards of temp. are based on freezing and boiling point of water
Celsius scale, freezing point is 0 and boiling point is 212
Absolute (Kelvin) scale reads 273 degrees higher than Celsius scale
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Temp. Equivalents
Fahrenheit Celsius
- 212 100
- 98.6 37
- 32 0
- 0 -32
- -40 -40
- -459 -273
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Matter
Anything that occupies space and has mass
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Physical Properties
Without change in chemical composition including color, taste, solubility, density, hardness, melting and boiling point
Freezing /melting point @ equilibrium
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State of Matter
Solid, Liquid, Gas and Plasmas
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Solubility
How well two substances mix; ability to go into solution
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Density
Ratio of mass of substance to its volume; D = m/v
Greater density, heavier object per unit of volume
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Specific gravity
Ratio of densities with water as standard
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Chemical Properties
Characteristic observed when substance is interacting with other substances resulting in change in chemcal composition
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Changes in matter
New substance or substances are produced that have entirely different properties from original substance because chemical composition has changed
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Physical Change in matter
Change in form of state of matter without any change in chemical composition
Changes in state - Solid, Liquid, Gas
Solvation (dissolving)
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Solvation (dissolving)
Going into solution; salt in water
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Chemical Changes in matter
New substance or substances are produced that have entirely different properties from original substance because chemical composition has changed; souring of milk
- Creamation of remains
- Decomposition of remains
- Embalming of remains
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Gases
State of matter having ability to diffuse; no definite shape or volume and assume shape and volume of container
- Liquefaction - become liquid
- Condensation - change of state from gas to liquid
- Vaporization - physical change from liquid (or solid) to gas
- Diffusion
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Diffusion
Movement of molecules or other particles in solution from area of greater concentration to area of lesser concentration until uniform concentration or equilibrium is reached
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Liquids
Substance with ability to flow and does not expand indefinetely
- Viscosity - resistance to flow
- Surface tension - force acts on surface of liquid tends to minimise surface area
- Diffusion
- Solidification - conversion of liquid or gas to solid
- Crystallization - substance given definite form or shape
- Freezing - from liquid to solid
- Boiling - rapid passage of liquid to vapor state ; Vapor = gaseous state
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Solids
Condensed state of matter having definite (fixed) shape and volume
- Melting - from solid to liquid
- Sublimation - solid to gas without passing through liquid state, result of absorption of heat
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Plasmas
4th state of matter; refers to ionized gas; electrically conductive so it responds strongly to electromagnetic fields; properties unlike those of sloids, liquids, or gases, distinct state of matter; typically takes form of neutral gas-like clouds
most common phase of matter in universe, both by mass and by volume
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Types of matter based upon composition
Elements, compounds, mixtures
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Elements
Simple (pure) substance that cannot be decomposed by ordinary chemical means, basics of which all matter is composed
Building blocks of all matter
Properties give them definite place on Periodic Table of Elements
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Symbol
Each element is represented by a symbol
First letter of name of element, or first two letters, or first letter and one other letter to suggest sound that is apparent in name
First letter is capitalized, second is not
Some based upon their Latin names
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Compounds
Substance consisting of two or more atoms combined chemically in definite proportions by mass
The more electro positive element named first, then add -ide or -ite, etc. to second
- Reactions known by equations (Na + Cl = NaCl)
- (2H + SO4 = H2SO4)
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Formula
Combination of symbols used to express chemical composition of substance; know compounds by the formula
Formula is Qualitative and Quantitative (what & how many) expression of compound
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Acids
Yeilds hydrogen or hydronium ions in aqueous solution; donates proton, accepts pair of electrons; pH less than 7
Every acid has hydrogen
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Bases
Yeilds hydroxide ions in aqueous solution; accepts proton, donates pair of electrons; pH more than 7
Every base has hydroxide
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Salts
Group of substances that result from reaction between acids and bases other than water
NaCl - Neither one is H or OH
HCl+NaOH = NaCl+HOH
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Oxides
Compound consisting of oxygen combined with only one other element
Fe23+O32- - CO2 - CO
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Mixture
Combination of two or more substances not chemically united and in no definite proption by mass
- Air- gas in gas
- Embalming fluid - varies with formula, gas in liquid
- Blood - colloidal suspension
- Concrete - sand, gravel and portland cement
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Energy
Ability of system or material to do work
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Potential Energy
Stored energy, energy at rest
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Kinetic Energy
Energy of body by virtue of its motion; speeding locomotive, an avalanche, falling water
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Atom
Smallest particle (unit) of an element that has all properties of the element
Comprised of Protons+, Neurtons+-, and Electrons
Change number of electrons and get ion of element; change number of neutrons and get isotope of element; cannot change number of protons and have same element
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Protons rule
Number of protons determines element
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Molecule
Smallest unit of compound which can exist alone; aggregation of atams, specifically chemical combination of two or more atoms which form specific chemical substance
Smallest unit of compound that retains all properties of compound
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Oxidation Number
Number used to represent number of electrons lost, gained or shared in chemical change
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Ion
Atomic or molecular species with positive (cation) or negative (anion) electrical charge
Atom that has lost or gained electron
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Chemical Elements
- Aluminum - Al
- Bromine - Br
- Calcium - Ca
- Carbon - C
- Chlorine - Cl
- Copper (element) - Cu
- Fluorine - F
- Helium - He
- Hydrogen - H
- Iodine - I
- Iron - Fe
- Mecury - Hg
- Nitrogen - N
- Oxygen - O
- Phosphorus - P
- Potassium - K
- Sodium - Na
- Sulfur - S
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Monatomic ion
Charged entity consisting of only single atom; atom (single) that has lost or gained electron
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Polyatomic ion
Group of atoms that act as unit and possess charge; radical
- Ammonium - formula NH4+1
- Bicarbonate - formula HCO3-2
- Hydroxide - formula OH-1
- Hypochlorite - formula OCl-1
- Phosphate - formula PO4-3
- Sulfate - formula SO4-2
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Solutions
Homogeneous mixture of one or more substances (solutes) dissolved in sufficient quantity of solvent
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Solute
Substance (solid, liquid, gas) dissolved in solvent to form solution
Component of solution present in lesser amount
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Solvent
Substance which does the dissolving in solution
Component of solution present in greater amount
Water = universal solvent
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Types of solution
Known (defined) by size of sloute particles
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True solution (crystalloid)
Mixture of two or more substances able to pass through semi permeable membrane
Size of solute particles is less than one nanometer; will never settle out of solution
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Colloid
Solution-like system in which size of solute particles is between 1 and 100 nanometers
Pass through filters but not membranes; will eventually settle out of solution
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Suspension
Mixture of solute and solvent in which size of solute particle is greater than 100 nanometers
Do not pass through filters or membranes
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Expressing concentrations
Ratio of solute to solvent
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Qualitatively
- Dilute
- Concentrated
- Saturated
- Unsaturated
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Dilute
Relatively small amount of solute
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Concentrated
Relatively large amount of solute
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Saturated
Containing all of solute the solvent is able to hold at certain temp. and pressure; dynamic equilibrium ( as much going in as going out)
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Unsaturated
Less solute than can be held in solution by solvent; not holding max amount of solute; not saturated, may be dilute or concentrated
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Quantitatively
Index as opposed to %; mixing units of measurement
Percent by weight and by volume
Ratios (1:1000)
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Allocation
Difference in each starting solution compared to ending solution and cross to opposite starting solution
- 35% - 5 parts
- 10%
- 5% - 25 parts
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Diffusion
Movement of molecules or other particles in solution from area of greater concentration to area of lesser concentration until uniform concentration is reached
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Factors influencing diffusion
Temperature - increase temp., increase rate of diffusion
Concentration of solute - more concentrated, more rapid diffusion
Size of molecular weight of solute - smaller molecule, faster diffuses
Agitation - stirring increase rate of diffusion; QSAD
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QSAD
Quantity Sufficient ADded
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Osmosis
Passage of pure solvent from solution of lesser solute concentration to one of greater solute concentration when two solutions are separated by semipermeable membrane which selectively prevents passage of solute molecules, but is permeable to solvent
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Hypotonic
Lesser concentration of dissolved solute; RBC swell and burst (hemolysis)
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Hypertonic
Greater concentration of dissolved solute; RBC shrivel and shrink (crenation)
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Isotonic
Equal concentration of dissolved solute; as much solution flows in as out
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Solubility
How well two substances mix; ability to go into solution
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Selected Elements
OIL RIG - Oxidation is Loss (of electron), Reduction is Gain (of electron)
Oxidation is a gain in positive valence, Reduction is gain in negative valence
- Oxygen
- Hydrogen
- Halogens
- Nitrogen
- Others
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Oxygen (occurrence)
Most abundant element on earth's surface
Oxidizing agent is one being reduced; Reducing agent is one being oxidized
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Oxidation
Combination of substance with oxygen or some other non metal; increase in oxidation number (gain positive valence); loss of electrons, electron donor
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Reduction
Decrease in oxidation number (increase negative valence); gain of electrons (electron receiver); combination of substance with hydrogen or some other metal
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Combustion
Rapid oxidation (burning) produces heat and light
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Hydrogen
No neutrons; most abundand element in universe
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Halogens
Salt formers; extremely poisonous
- Chlorine, fluorine, bromine, iodine - all 1 - oxidation state
- Excellent disinfectants
- Chlorine as bleaching agent, bleaches by oxidation
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Nitrogen (occurrence)
Most abundant element in earth's atmosphere; Nitorgen neutralizes aldehydes
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Metal (other selected element)
Element marked by luster, malleability, ducility, conductivity or electricity and heat; form positive ions
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Nonmetal (other selected element)
Element that is not a metal; form negative ions
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Selected Compounds
- Water (universal solvent)
- Ammonia
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Water (universal solvent)
Most abundant compound on earth's surface
H2O (emperical formula); pH of 7 (as much H as OH)
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Desiccation
water has been removed
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Water Hardness
Condition of water which results from dissolved minerals and metallic ions such as calcium and magnesium
Temporary hardness if bicarbonate ions will boil away
Permanently hard if present as chlorides
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Hydrates (holds water)
Is chemical union between water and certain other substances when they crystallize; wet and gooey
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Hydrolysis
Chemical reaction which substance is broken down or dissociated by water, reaction between salt and water to yeild an actid and base of unequal strengths (NaCl+HOH = NaOH+HCl)
Opposite of neutralization reaction
Breaking down by taking in element of water
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Dehydration
Removal of water
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Synthesis
Combine by taking water out
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Ammonia (NH3)
Stable compound; Ammonium ion (NH4) not stable
Decomposition product of proteins
Neutralization with formaldehyde; results in urotropin (a.k.a methenamine & hexamethylenamine) C6H14N4
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Ionization
Dissociation of substance in solution into ions
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Ion
Atom that has gained or lost electron becoming charged particle
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Acids (Ionization)
Yeilds hydrogen or hydronium ions in aqueous solution
Donates proton; accepts pair of electrons
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Bases (Ionization)
Yeilds hydroxide ions in aqueous solution
Accepts proton; donates pair of electrons
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Salts (Ionization)
Group of substances that result from reaction between acids and bases other than water
Product of neutralization reaction
Compound of 2 or more elements, neither one H or OH
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Cation
Positively charged atom or group of atoms
Cathode = Negative charge (-) to attract positively charged ions
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Anion
Negatively charged atom or group of atoms
Anode = Positive charge (+) to attract negatively charged ions
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pH: Acid/Base scale
Scale of 1-14, 7 being neutral
As much acid as base" H - OH
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Neutralization
Reaction of acid and base to produce salt and water
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Radioactivity
Property causes element to emit radiation from nucleus of atom
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Types of radiation
- Alpha particles
- Beta particles
- Gamma rays
- X-rays
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Units of radiation
- Curie
- Roentgen (R)
- Rad (radiation absorbed dose)
- Rem (radiation equivalent, man)
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Curi
Unit of radiation
Number of nuclear disintegrations occurring per second
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1 Curie (1 Ci)
37 billion
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1 millicurie (1mCi)
37 million
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1 microcurie (1uCi)
37,000
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Roentgen (R)
X-rays and gamma rays only
Intensity of X-rays and gamma rays that produces 2 billion ion pairs in 1 ml. of air
Not used to measure radiation in tissues
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Rad (radiation absorbed dose)
Amount of radiation energy absorbed by tissue
Absorption of 100 ergs of energy per gram of tissue
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Rem (radiation equivalent, man)
Amount of radiation absorbed by human being
Ionizing radiation that has effect equal to absorption of 1 Roentgen
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Detection and measurement of radiation
Geiger counter
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Raioisotopes
Medically, diagnosis and treatment of disorders
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Half-life
Amount of time required for half of atoms in sample to decay
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Radioisotopes used in medicine
- Iodine-131
- Iodine-123
- Technetium-99m
- Cobalt-60
- Cobalt-57
- Phosphorus-32
- Radium-226
- Gold-198
- Strontium-89
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Radiation Protection
Shielding, distance, limiting time of exposure
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Sources of radiation
- Natural background radiation
- Medical radiation
- Radioactive wastes
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Release of body with radioactivity
Un-autopsied - 30 millicuries
Autopsied - 5 millicuries
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Properties of carbon
Comnining capacity - will form 1,2 or 3 bonds (single, double or triple covalent bonds) with another carbon; will share four electrons with 2 - 4 other elements
C-C, C=C and C=_C (double and triple bonds less stable)
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Isomerism
Possession by two or more distinct compounds of same molecular formula, each molecule having same number of atoms of each element but in different arrangement
Same molecular formula with different structural, physical arrangement
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Allitropism
Existing in more than one elemental form, such as Coal, Diamond, and Graphite
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# Carbons
- 1 Methyl
- 2 Ethyl
- 3 Propyl
- 4 Butyl
- 5 Pentyl
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OH
Alcohol group (in organic chemistry)
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Formulas (organic chemistry)
Combination of symbols used to express chemical composition of substance
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Molecular (Empirical) formulas
Expressing number of atoms of each element present in molecule of substance, without indicating how they are linked
Whats's present and how many of each
C2H6O
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Structural formulas
Showing spatial relationship between substituent atoms in molecule; who's holding hands with who
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Line formulas
Condensed version of structural formula written all on one line still showing relationship between substituents groups in molecule
CH3CH2OH; HCHO
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General formulas
Denotes class of compounds and includes functional group and symbol (R) denoting alkyal radical
Capital "R" = general formula
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Classes of organic compounds
- Hydrocarbons
- Alcohols
- Aldehydes
- Ketones
- Carboxylic acids
- Esters
- Ethers
- Amines
- Amides
- Thioalcohols (Mercaptans)
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Hydrocarbons
Contains only carbon and hydrogen
May be Alophatic - straight chain, or Cyclic - circular
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Saturated Hydrocarbons
Only single bonds between carbons
- Alkanes
- Alkyl group
- Alkyl halide
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Alkanes
Saturated hydrocarbon; single bonds only
Type formula - C nH 2n+2 (N=Carbons). Multiply by 2, add 2 Hydrogens
- Methane - CH4, simplest alkane, 1 carbon
- Ethane - C2H6, 2 carbon alkane
- Propane - C3H8, 3 carbon alkane
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Alkyl group
Monocalent radical of general formula CnH2n+1; alkane loses one hydrogne atom
CH3- - simplest methy group
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Alkyl halide
One or more halogen atoms attached; X represents alkyl halide
R-X = general formula (CH2X2 - Chloroform)
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End in __ Carbons have
-ane Single bond
-ene Double bond
-yne Triple bond
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Unsaturated Hydrocarbons
Containing carbon and hydrogen, one or more double or triple bonds between two carbon atoms
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Unsaturated Alkenes
Hydrocarbon containing double bond between carbons
Type formula - CnH2n (# carbons multiplied by 2 = # hydrocarbons)
Ethene - C2H4 - simplest alkene
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Unsaturated Alkynes
Hydrocarbon containing triple bond between carbons
Type formula - CnH2n-2 (# carbons multiplied by 2, minus 2 = # hydrocarbons)
Ethyne (acetylene) - C2H2 - simplest alkyne
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Aromatic Hydrocarbons
Special class of cyclic compounds containing benzene ring as parent structure
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Benzene
C6H6 - simplest form - six-sided surrounded by Hydrogen
Parent structure of all aromatic compounds
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Toluene
C6H5CH3; methyl group (CH3) replaced hydrogen
Methyl derivative of benzene
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Alcohols
Containing one or more hydroxyl (-OH) group
General formula for monohydroxy alcohol is R-OH (R = hydrocarbon group)
Classification = Primary, Secondary, Tertiary
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Primary Alcohol
Functional group (OH) attached to hydrogen, or no more than one other carbon
- Methanol, methyl alcohol, wood alcohol (1 Carbon)
- Ethanol, ethyl alcohol, grain alcohol (2 Carbon)
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Secondary Alcohol
Isopropyl alcohol (propanol), rubbing alcohol
Minimum or 3 carbons; acive group (-OH) attached to carbon attached to two other carbons
C-C-C-OH
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Tertiary Alcohol
Monohydroxy alcohol which hydroxyl group (-OH) is attached to carbon attached to three other carbons
Tertiary Butyl Alcohol - simplest
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Iso
Same, Isosceles triangle
Iso - (propyl, pentyl, etc.); must be odd # of carbons with functional -OH group attached to middle carbon
- H OH H
- H - C - C - C - H
- H H H
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Dihydroxy Alcohol
Ethylene glycol - simplest
All glycols have 2 OH groups (antifreeze)
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Polyhydroxy Alcohol
Sorbital (6 carbon)
6 OH groups; best humectant
- OH OH OH OH OH OH
- C - C - C - C - C - C
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Phenol or Carbolic Acid
Excellent preservative, won't coagulate, simplest aromatic
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# Carbons
- Meth - 1 Wood alcohol
- Eth - 2 Grain alcohol
- Prop - 3 Tri
- Butyl - 4 (any time after 1, usually 4 or more)
- Penytl - 5
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Aldehydes
Containing one or more -CHO groups
General formula - R-CHO (R = hydrocarbon or hydrogen)
Partial oxidation of primary alcohol like methanol
Methanal, formaldehyde, simplest
Ethanal
Benzaldehyde
Dialdehydes
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Methanal, Formaldehyde
Formula - HCHO
Preparation - methane oxidized to methanol (wood alcohol), methanal (formaldehyde), methanoic acid (formic), CO2, H2O, energy
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Properties of Formaldehyde
- Colorless gas
- Irritating odor
- Soluble in water
- Readily oxidized to formic acid
- Polymerization to paraformaldehyde (paraform)
- Index
- Formaldehyde Strong Reducing Agent
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Polymerization
Linking together of monomers to form polymer; HCHO in sold form
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Index
Strength of embalming fluids in 100 ml of solution; % HCHO in solution
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Uses of formaldehyde
Coagulated proteins
Disinfectant, Neutralized by Ammonia, Preservative
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Preservative
Inactivate active chemical groups of proteins and amino acids; inhibit decomposition; kill microorganisms; destroy odors and eliminate further formation; inactivate enzymes
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Formalin
Formaldehyde gas dissolved in water at highest concentration
37% by weight; 40% by volume
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Ethanal
Acetaldehyde - 2 carbon (CH3CHO)
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Benzaldehyde
Aromatic - 7 carbon
Benzene ring with aldehyde (-CHO) attached
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Dialdehydes
Containing two aldehyde (-CHO) radicals
Glyoxal - 2 carbons
Glutaraldehyde - 5 carbon dialdehyde
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Glyoxal
2 carbon
Ethalene Glycol oxidized to Glyoxal
Simplest dialdehyde
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Glutaraldehyde
5 carbon dialdehyde on ends of group; good disinfectant
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Ketones
Containing carbonyl group (C=O) whose carbon atom is joined to two other carbons; carbonyl group occurs within carbon chain
Partial oxidation of secondary alcohol; 3rd carbon in middle; solvents
one = ketone
General formula - R-CO-R
Propanone or acetone - simplest ketone
Ketone is last step in oxidation series for secondary alcohol
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Carboxylic acids (organic acids)
Containing carboxyl group OH (-COOH); very weak acids
Partial oxidation of aldehydes
General formula - R-COOH
Methanoic or formic acid (HCOOH)
Ethanioc or acetic acid; 2 carbon - CH3COOH (vinegar)
oic = carboxylix acid
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Esters
General formula RCOOR' (R is hydrocarbon or hydrogen, R' is hydrocarbon)
Formed from alcohol and organic (or carboxylic) acid by removal of water (dehydration synthesis)
Acid with alcohol
ate = ester
General formula - R-COO-R; fruity odor, masking agent
- Ethyl acetate (ethyl alcohol and acidic acid)
- Methyl salicylate (windergreen)
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Esterification
Making ester from alcohol and organic acid by removal of water
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Ethers
General formula - R-O-R' (R and R' are hydrocarbon formed by dehdration between two alcohols)
Alcohols and Ethers only structures without carbonyl carbon (C=O), no double bond
Diethyl ether (sleep); 4 carbon CH3CH2OCH2CH3
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Amines
Containing Nitrogen; any group formed from ammonia by replacement of one or more hydrogen atoms by organic radicals
General formula for primary amines - R-NH2
Properties - Alkaline (basic), Disagreeable odor, Decomposition products of protein
Neutralizes formaldehyde
Methyl amine (CH3NH2) - simplest amine
Quaternary ammonium compounds
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Quaternary ammonium compounds
"Surface-active agents", counter top or surface of body
Disinfection of skin, oral and nasal cavities and instruments; topical disinfectant
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Amides
Derived from ammonia by substitution of carbonyl group (C=O, double bonded oxygen) for hydrogen, or from acid by replacing -OH group by amino group (-NH 2)
Decomposition of proteins
HCO OH + NH 3 = HCONH 2
General formula - R-CONH-R
- Dimethylformamide - solvent for chemical reactions
- Urea - simple amide
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Thioalcohols (Mercaptans)
General formula - R-SH
Similar to alcohol which oxygen of hydroxyl group is replaced by sulfur (-SH); Sulfur containing compounds products of decomposition
Disulfide - H - S - S - H or R - S - S - R'
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Carbohydrates
C, H, and O in all cases, aldehyde or ketone derivative of polyhydroxy alcohol
Sugars, starches, glycogen
Cellulose
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Cellulose
Complex carbohydrate, most abundant compound in biosphere
-ose = sugar
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Carbohydrates Classification
Monosaccharides
Disaccharides
Polysaccharides
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Monosaccharides
Simple sugars; final hydrolytic products of polysaccharides or complex sugars
Final oxidation - CO 2 + H 2O + Energy
- Aldose
- Ketose
- Pentose
- Hexose
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Aldose
Monosaccharide sugar; hydroxyl (-OH) and aldehyde (-CHO) on end carbon
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Ketose
Monosaccharide sugar; hydroxyl (-OH) and ketone C=O attached to secondary carbon
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Pentose
Monosaccharide sugar; 5 carbon sugar molecule
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Hexose
Monosaccharide sugar; 6 carbon sugar molecule; most abundant type of sugar
- Glucose - molecular formula C6H12O6; Aldose sugar
- Fructose - fruit sugar
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Disaccharides
Two monosaccharide units
Molecular formula - C 12H 22O 11 (water taken out); Hydrolyze to yeild 2 monosaccharides (2 C 6H 12O 6)
- Sucrose - table sugar (mixture glucose & fructose)
- Lactose - milk sugar
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Polysaccharides
Number of simple sugar molecules; Starches and cellulose; many sub-units
- Starch - plants store energy as starch
- Glycogen - animal starch; chains of alpha glucose molecules (Humans store sugar as glycogen)
- Cellulose - most abundant compound in biosphere
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Cellulose
Polysaccharide; most abundant compound in biosphere
Structural substance of plants, not affected by enzymes (cannont be digested by humans)
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Reactions of Carbohydrates
Final Hydrolysis Products - Monosaccharides
Final oxide - CO2 + H2O and energy
Fermentation - Decomposition
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Fermentation - Decomposition
Anaerobic process takes place in presence of enzyme (generally from yeast); C6H12O6 - C2H6O [CH3CH2OH (Ethyl alcohol)]
Chemical reactions induced by living nonliving ferments that split complex organic compounds into relatively simple substances
Anaerobic conversion of sugar to carbon dioxide and alcohol by yeast
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Lipids
C, H, O in all cases
Fats, Oils, and Waxes
Simple and Compound lipids
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Simple Lipids
Hydrolytic products are fatty acids & alcohols
Triglyceride;
Hydrolytic products - 1 glycerol, 3 fatty acid
Final oxidation - CO2, H2O, Energy
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Fats & Oils Physical Properties
Fats - semi-soild; Oil - liquid; Wax - solid
Lipoproteins - proteins contain fat
Emulsification
Final Hydrolytic - 1 Glycerol, 3 fatty acids
Final Oxidation - CO2, H2O, Energy
Saponification
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Fat
Triacylglycerol that is semisolid or solid at room temp., contains high percentage of saturated fatty acids; Animals
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Oil
Triacylglycerol that is liquid at room temp., contains high percentage of unsaturated fatty acids; Plants main source
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Emulsification
Mixing two insoluble liquids; break down large molecule into small ones that are suspended in solution
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Bile
Produced in liver, stored in gall bladder; holds fats in solution
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Saponification
Reaction between fat and stron base to produce glycerol and salt of fatty acid (soap); soap formation; Adipocere
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Adipocete
Gravewax - wax-like material produced by saponification of body fat in body buried in alkaline soil; more corpulent person, greater effect
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Waxes
Lipid formed from combination of unsaturated and/or saturated fatty acids and high-molecular-weight alcohols (not glycerol)
Solid at room temp.
1 monohydroxy alcohol, 1 fatty acid
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Compound Lipids
Lipid whose hydrolytic producs are fatty acids, alcohol, and other substances
C, H, O, S and P (Sulfur and Phosphorus)
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Proteins
Biological compound that is polymer of many amino acids; most abundant compound in body (other than water); Glycoproteins
C, H, O, N in all cases
Final hydrolytic products - Amino Acids
Final Oxidation - CO2, H2O, N (Nitrogenous products), Energy
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Glycoproteins
Proteins that contain carbohydrates
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Amino Acids
Building blocks of proteins; compound containing amino group (-NH2), carboxyl (-COOH [C=O)], and radical
Glycine - simplest
Properties of amino acids - Amphoteric, Allotropism
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Amphoteric
Compound that can act as both acid and base
Ammonia (NH2) is basic while COOH is Acidic
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Allotropism
Existence of element in two or more distinct forms
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Buffers
Substances in solution capable of neutralizing both acids and bases, thereby maintaining original (or constant) pH of solution
Protiens act as buffers in aqueous solution
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Peptide Bond
Dehydration reaction between amino group on one amino acid with carboxyl (organic acid) group on other amino acid
Holds amino acids together in protein; hooks amino end to carboxyl end of different amino acid
Dipeptide - 2 amino acids hooked together
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Properties of Proteins
- Imbibition
- Coagulation
- Final Hydrolysis Products - Amino Acids
- Deamination
- Decarboxylation
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Imibition
Swelling and softening of tissues and organs as result of absorbing moisture from adjecent sources; Hold in water
Imbibe - to drink
Proteins have ability to hold large amount of water
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Coagulation
Converting soluble protein to insoluble protein by heating or contact with chemical such as alcohol or aldehyde
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Deamination
Removal of amino (-NH2) group from compound (amino acid)
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Decarboxylation
Removal of carboxyl (-COOH) group from compound (amino acid); cannot preserve at this point of decomp.
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Enzymes
Protein acts as biological catalyst; Organic catalysts produced by living organisms
-ase = enzymes
Autolysis - self-digestion
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Catalyst
Substance that changes rate of chemical reaction but undergoes no net change intself during reaction
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Biocatalitic
Catalyst of plant or animal origin
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Enzyme Chemical Properties
Protein constitution - made of protien
Specificity - Very; act on one substrate only
High temp. coagulates
Chemically labile (denaturation)
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Chemically labile (denaturation)
Disruption and breakdown (unfolding) of secondary structure of protein by heat of chemicals; ruins
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Autolysis
Self- digestion or self-destruction of body by autolytic enzymes; Enzymes are necessary for body to eat itself
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