kinetics
Card Set Information
Author:
broach13
ID:
189156
Filename:
kinetics
Updated:
2012-12-12 19:11:55
Tags:
ch12
Folders:
Description:
kinetics
Show Answers:
zero-order differential law
rate = k
zero-order integrated
[A] = -kt + [A]o
Relationship needed to give a linear graph of the rate constant for zero-order
[A] vs t
slope of graph for zero-order reaction
-k
half-life of zero-order
rate law for first order
rate = k[A]
integrated first-order
ln[A] = -kt + ln[A]o
plot for a linear first-order reaction
ln[A] vs t
slope of first-order plot
-k
half-life of first-order
ln2/k
rate law for second-order
rate = k[A]^2
integrated second-order
1/[A] = kt + 1/[A]o
plot for linear second-order
1/[A] vs t
slope of second-order plot
k
half-life of second-order