CHEM12C Midterm 1

Home > Preview

The flashcards below were created by user daynuhmay on FreezingBlue Flashcards.


  1. aldehyde suffix
    -al
  2. ketone suffix
    -one
  3. -OH -> =O

    (alcohol oxidation)
    PCC, CH2Cl2
  4. Ph-OH -> Ph-=O

    (benzyllic oxidation)
    MnO2
  5. hydrate formation:
    Image Upload
    H2O + [H+ OR -OH]
  6. acetal formation:
    Image Upload
    2CH3OH + H+
  7. cyclic acetal formation (Grignard protection):
    Image Upload
    HOCH2CH2OH + H+ cat
  8. deprotection:
    Image Upload
    H+, H2O
  9. Image Upload
    Image Upload
  10. Image Upload
    R"NH2, 1% AcOH
  11. Image Upload
    R2NH, 1% AcOH
  12. Wolff-Kishner Reduction:
    Image Upload
    H2N-NH2, KOH, Image Upload
  13. Image Upload
    Image Upload
  14. Phosphorus ylide synthesis (for Wittig rxn):
    Image Upload
    • 1. Ph3P
    • 2. nBuLi
  15. aldehyde/ketone + H2O=
    hydrate
  16. aldehyde/ketone + 2ROH =
    acetal
  17. aldehyde/ketone + NH3/1oR-NH2 =
    imine
  18. aldehyde/ketone + 2RR'NH =
    enamine
  19. aldehyde/ketone + N2H4 =
    alkane
  20. Image Upload
    MgBrR", aq. workup
  21. Image Upload
    Image Upload
  22. Bayer-Villager Oxidation:
    Image Upload
    • ketone -> ester
    • Image Upload
  23. During Bayer-Villager oxidation, which Image Upload-carbon undergoes alkyl migration?
    the more substituted one
  24. Image Upload
    Image Upload

    **Ag2O selectively oxidizes aldehydes over alcohols to RCO2H
  25. Image Upload
    PCC, H2O
  26. Image Upload
    Image Upload
  27. Image Upload
    • 1. Mg
    • 2. O=C=O  (CO2)
  28. Image Upload
    • 1. O3
    • 2. H2O
  29. Image Upload+ NH4+
    H+, H2O, Image Upload
  30. Image Upload+ NH3
    NaOH, H2O, Image Upload
  31. Image Upload
    SOCl2, pyr
  32. Image Upload
    Image Upload
  33. Image Upload
    H+, ROH
  34. Image Upload
    CH2N2
  35. carboxylic acid suffix
    -oic acid

    ex: alkane -> alkanoic acid
  36. amide suffix
    remove -oic acid and replace with -amide

    ex: hexanoic acid -> hexanamide
  37. ester suffix
    remove -oic acid and replace with -oate

    ex: pentanoic acid -> pentanoate

Card Set Information

Author:
daynuhmay
ID:
218587
Filename:
CHEM12C Midterm 1
Updated:
2013-05-09 09:22:15
Tags:
ochem
Folders:

Description:
ochem
Show Answers:

Home > Flashcards > Print Preview