ochem ch 8 reactions of alkenes part 2 (addition, electrophilic, pi bond, hydration, halogenation, h

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mikepl103
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244237
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ochem ch 8 reactions of alkenes part 2 (addition, electrophilic, pi bond, hydration, halogenation, h
Updated:
2013-11-09 16:18:08
Tags:
ochem reactions alkenes part addition electrophilic pi bond hydration halogenation hydrogenation Markovnikov rule regiochemistry oxymercuration demercuration
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ochem ch 8 reactions of alkenes part 2 (addition, electrophilic, pi bond, hydration, halogenation, hydrogenation, Markovnikov's rule, regiochemistry, oxymercuration-demercuration)
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  1. Markovnikov's rule doesn't apply during a ____-____ _____ __ ___
    free-radical addition of HBr
  2. In the following reaction, where will the Hg(OAc) and the alcohol be added?

  3. can rearrangement take place in hydration
    rearrangement may take place during hydration
  4. can rearrangement take place during acid-catalyzed hydration?
    yes, rearrangement can take place
  5. is hydroboration a syn or anti addition?
    syn, meaning that the OH and the H add to the same side
  6. Is hydroboration stereospecific?
    yes
  7. is hydrogenation syn and anti addition?
    syn
  8. What is the mechanism for hydrogenation?
  9. example of a carbene addition:
  10. what are the three ways by which a carbene (or carbenoid) can be formed?
    heating or photolysis of diazomethane, simmons-smith reaction, and alpha elimination
  11. If cyclohexane reacted with CHCl3 and 50% NaOH/H2O, what would be the product?

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