solid segmented in ordered regions - called grains
Grains
defective regions
Interstitial defect
atoms that occupy a site in the crystal structure at which there is usually not an atom
Frenkel defect
a nearby pair of a vacancy and an insterstitial
Shottky defect
a pair of vacancies
Edge dislocation (line)
the termination of a plane of atoms in the middle of a crystal
Screw dislocation (line)
helical path traced around line defect
Thermal activated process
is one in which the system must overcome an energy barrier in order for the process to go forward
Diffusion
the passive movement of molecules or particles along a concentration gradient, or from regions of higher to lower concentration
Solid solution
(of two metals)... one metal is the "host" (and the other the "impurity", then the addition of the "impurity" metal will cause an increase in the resistivity and make the total resistivity less and less temperature dependent.
Isomorphous phase diagram
a phase diagram for an alloy that has an unlimited solid solubility... //same morphology everywhere
Phase
a HOMOGENEOUS portion of a chemical system that has the same structure, composition and properties everywhere
Nucleation
initial crystal formation
Isotherm
a horizontal line on a phase diagram
Solidus curve
line separating solid phase from mixed phase
Mean free path
mean scattering time/relaxation time
Mobility
expresses how "easy" electrons can move (drift) under the influence of an electric field; it is directly related to relaxation (or mean scattering) time
Conductivity
the ability of a solid to conduct electricity (cousin of mobility)
Covalent bond
sharing of electrons... between atoms to complete outer shells
Ionic Bond
transfer of charge; i.e. electron transfer from one atom to the other creating ions;
Metallic bond
atoms (of metals) give easily valence electrons to the solid (sharing of "free" electrons)
Diamond lattice
Si, Ge; Zincblend when two atoms GaAs (two interpenetrating fcc's displaced by ΒΌ a
Work function
minimal amount of energy required to remove an electron from a metal to a vacuum
Orbital
region of a space in an atom or molecule in which an e- with a given energy may be found
Light Intensity
more light "particles"
Photon
a light particle//a quantum of energy
Pauli Exclusion Principle
NO two electrons can have the same set of quantum numbers
Hund's Rule
All of the electrons in a singly occupied orbitals have to keep their spin parallel//same spin
Diffraction
the bending of waves due to interaction with objects of size similar to its wavelength
Space Quantization
the quantization of one or more components of the angular momentum of a system
Energy Quantization
the concept refers to how electrons can only exist in different energy levels. Their existence in the energy levels defines atoms.
Wavefunction
probability function that describes a particles wave like behavior
Quantization
the act of dividing into quanta or expressing in terms of quantum theory
Tunneling
If an electron comes up a potential barrier greater than its energy... there is a finite probability that it will "pass" through the barrier
Bohr Radius
the radial distance where the radial probability is maximum
LASER
light amplification by stimulated emission of radiation
Ground state
lowest energy/n=1 state
Heisenberg's Uncertainty Principle
The position and momentum of a particle cannot be simultaneously measured with high precision
Schrodinger Equation
describes how the quantum state of some physical system changes with time.
ih(part d/part dt)w= Hw
state
description of a system in terms of parameteres
Density of states
the number of available electronic states per unit volume per unit energy
Seebeck Effect
Net diffusion of electrons from the "hot" to the "cold" region of a metal
Effective electron mass (m_o)
the mass of a particle that it seems to have when responding to forces, or the mass that it seems to have when en masse with other identical particles in a thermal distribution