BME418 Ch. 6 (3)

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khaengel
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284452
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BME418 Ch. 6 (3)
Updated:
2014-09-29 23:53:15
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BME418
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  1. The law of equi-partition of energy (one of the principal results of statistical mechanics): the average energy associated with every degree of freedom is
  2. Chemical potential of a dilute solution, the chemical energy is expressed in terms of free energy:
  3. The free energy is composted of water free energy, solute energy, and a mixing entropy term due to possibility of rearranging the solute molecules:
  4. To calculate the mixing entropy (configurational entropy), we first examine the number of ways of distributing the water and solute molecules. Using the lattice model, we have:
  5. Chemical potential of a dilute solution determine the entropy is obtained from Boltzmann entropy formula:
  6. Chemical potential of a dilute solution total free energy:
  7. Chemical potential within a dilute solution:
  8. In general, the chemical energy is related to the logarithmic function of solute concentration:

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