Organic Chemistry 2: Ch 17-18

The flashcards below were created by user worthingrocks on FreezingBlue Flashcards.

  1. Grignard add to carbonyl form what?
    • Image Upload
    • Alcohols
  2. Borohydride with carbonyl
    Image Upload
  3. grignard with with carbonyl, followed by acid
    Image Upload
  4. Solvent to make Magnesium Grignard Reagent
    • Image Upload
    • Copper compounds require pentanes or hexanes
  5. grignard plus aldehyde
    • Image Upload
    • secondary alcohol
    • formaldehyde makes primary alc
    • ketone makes tertiary alc
  6. grognard plus carbon dioxide
    Image Upload
  7. cyanohydrin plus acid, water, and heat
    • Image Upload
    • lookup mechanism on power points
  8. cyanide with Hydrogen over nicke
    Image Upload
  9. cyanide plus carbonyl
    Image Upload
  10. carbonyl plus 2eq of grignard
    Image Upload
  11. 2eq of borohydride plus carbonyl
    Image Upload
  12. ester plus AlH4 (hydride)
    Image Upload
  13. car box acid plus AlH4 Mech (research arrows if uncertain)
    Image Upload
  14. benzamide plus 1.LiAlH4, 2.H20
    Image Upload
  15. carbonyl plus H2 raney nickel
    Image Upload
  16. carbonyl plus sodium borohydride plus water
    Image Upload
  17. aldehyde plus primary amine (trace acid)
    Image Upload
  18. cyclohexanone plus secondary amine (trace acid)
    Image Upload
  19. cyclohexanone plus amine plus trace acid, followed by NaBH3CN
    Image Upload
  20. carbonyl plus water plus acid
    Image Upload
  21. carbonyl plus methanol plus acid, followed by more methanol and acid.. basically 2eq of each
    Image Upload
  22. double ester plus water and acid
    Image Upload
  23. protective groups
    Image Upload
  24. carbonyl plus peroxide carbonyl
    • Image Upload
    • Image Upload
  25. ketone plus CF3C=OOO-
    Image Upload
  26. witting reaction mechanism intermediate
    • Image Upload
    • attack carbonyl to form this
    • then break two bonds to form product
  27. 4 addition of Nu to Carbonyl
    (remember 1 starts on O)
    Image Upload
  28. weak base conjugate addition
    Image Upload
  29. difference between MgBr addition and CuLi addition
    Image Upload
  30. where does a nucleophile attack a carbonyl?
    the carbonyl compound
  31. where does a base attack a carbonyl
    takes Alpha-carbon's H
  32. keto-enol tautomer
    Image Upload
  33. halogenated with acid catalyst
    • Image Upload
    • Image Upload
  34. base promoted halogenation
    Image Upload
  35. Why Use LDA?
    Image Upload

    Image Upload
  36. LDA to ketone, followed by bromoethane
    Image Upload
Author:
worthingrocks
ID:
297013
Card Set:
Organic Chemistry 2: Ch 17-18
Updated:
2015-02-28 20:48:38
Tags:
organic chemistry mechanisms mechanism worthingrocks zhu toledo university
Folders:

Description:
organic chemistry
Show Answers: