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The flashcards below were created by user
worthingrocks
on FreezingBlue Flashcards.
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Grignard add to carbonyl form what?
 - Alcohols
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Borohydride with carbonyl
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grignard with with carbonyl, followed by acid
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Solvent to make Magnesium Grignard Reagent
 - Copper compounds require pentanes or hexanes
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grignard plus aldehyde
 - secondary alcohol
- formaldehyde makes primary alc
- ketone makes tertiary alc
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grognard plus carbon dioxide
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cyanohydrin plus acid, water, and heat
 - lookup mechanism on power points
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cyanide with Hydrogen over nicke
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carbonyl plus 2eq of grignard
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2eq of borohydride plus carbonyl
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ester plus AlH4 (hydride)
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car box acid plus AlH4 Mech (research arrows if uncertain)
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benzamide plus 1.LiAlH4, 2.H20
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carbonyl plus H2 raney nickel
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carbonyl plus sodium borohydride plus water
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aldehyde plus primary amine (trace acid)
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cyclohexanone plus secondary amine (trace acid)
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cyclohexanone plus amine plus trace acid, followed by NaBH3CN
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carbonyl plus water plus acid
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carbonyl plus methanol plus acid, followed by more methanol and acid.. basically 2eq of each
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double ester plus water and acid
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carbonyl plus peroxide carbonyl
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witting reaction mechanism intermediate
 - attack carbonyl to form this
- then break two bonds to form product
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4 addition of Nu to Carbonyl
(remember 1 starts on O)
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weak base conjugate addition
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difference between MgBr addition and CuLi addition
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where does a nucleophile attack a carbonyl?
the carbonyl compound
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where does a base attack a carbonyl
takes Alpha-carbon's H
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halogenated with acid catalyst
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base promoted halogenation
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LDA to ketone, followed by bromoethane
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