Organic Chemistry 2: Ch 17-18

  1. Grignard add to carbonyl form what?
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    • Alcohols
  2. Borohydride with carbonyl
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  3. grignard with with carbonyl, followed by acid
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  4. Solvent to make Magnesium Grignard Reagent
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    • Copper compounds require pentanes or hexanes
  5. grignard plus aldehyde
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    • secondary alcohol
    • formaldehyde makes primary alc
    • ketone makes tertiary alc
  6. grognard plus carbon dioxide
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  7. cyanohydrin plus acid, water, and heat
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    • lookup mechanism on power points
  8. cyanide with Hydrogen over nicke
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  9. cyanide plus carbonyl
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  10. carbonyl plus 2eq of grignard
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  11. 2eq of borohydride plus carbonyl
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  12. ester plus AlH4 (hydride)
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  13. car box acid plus AlH4 Mech (research arrows if uncertain)
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  14. benzamide plus 1.LiAlH4, 2.H20
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  15. carbonyl plus H2 raney nickel
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  16. carbonyl plus sodium borohydride plus water
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  17. aldehyde plus primary amine (trace acid)
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  18. cyclohexanone plus secondary amine (trace acid)
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  19. cyclohexanone plus amine plus trace acid, followed by NaBH3CN
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  20. carbonyl plus water plus acid
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  21. carbonyl plus methanol plus acid, followed by more methanol and acid.. basically 2eq of each
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  22. double ester plus water and acid
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  23. protective groups
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  24. carbonyl plus peroxide carbonyl
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  25. ketone plus CF3C=OOO-
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  26. witting reaction mechanism intermediate
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    • attack carbonyl to form this
    • then break two bonds to form product
  27. 4 addition of Nu to Carbonyl
    (remember 1 starts on O)
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  28. weak base conjugate addition
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  29. difference between MgBr addition and CuLi addition
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  30. where does a nucleophile attack a carbonyl?
    the carbonyl compound
  31. where does a base attack a carbonyl
    takes Alpha-carbon's H
  32. keto-enol tautomer
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  33. halogenated with acid catalyst
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  34. base promoted halogenation
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  35. Why Use LDA?
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  36. LDA to ketone, followed by bromoethane
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Author
worthingrocks
ID
297013
Card Set
Organic Chemistry 2: Ch 17-18
Description
organic chemistry
Updated