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Biochem rxns
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types of bond cleavages for C-H bonds
homo- each atom gets one electron
hetero-one atom gets both e- and one gets none
7 common rxns in biochemistry
Nucleophilic substitution
Aldol condensation
claisen condensation
Decarboxylation
internal rearrangments
Elimination rxns
Free radical rnxs
difference between aldol and claisen
aldol-c nuc w/ carbonyl + ketone= alcoholÂ
claisen-c nuc w/ carbonyl + ester=ketone
thiolase
claisen condensation
SH on enzyme+
enolase
water is removed from 2 phosphoglycerate to form phosphoenolpyruvate (double bond)
elimination rxn
isomerization mech
base attracts proton opposite alcohol
forms double bond and another alchol
[two alcohols]
base attracts 1st alcohol H and forms double bond C-O abd hydrogen bond
Author
Sheilaj
ID
336016
Card Set
Biochem rxns
Description
stuff
Updated
2017-11-15T04:09:29Z
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