Phenol Reactions

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Author:
enger91
ID:
85267
Filename:
Phenol Reactions
Updated:
2011-05-11 17:36:23
Tags:
phenol
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Description:
University of MN Twin Cities, CHEM 2302
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  1. benzyl alcohol + PBr3->
    benzyl bromide
  2. phenol + PBr3->
    no reaction
  3. Williamson synthesis
    phenol + NaOH-> primary alkyl halide-> ether (benzene-O-R)
  4. phenol + NaOH, primary alkyl halide->
    ether
  5. phenol --> ether
    NaOH, primary alkyl halide
  6. Kolbe reaction
    phenol + NaOH, CO2, H3O+, pressure-> HO-benzene-COOH + acid chloride-> HOOC-benzene-OOC-R
  7. phenol --> HO-benzene-COOH
    NaOH, CO2, H3O+, pressure
  8. phenol + NaOH, CO2, H3O+, pressure->
    HO-benzene-COOH
  9. HO-benzene-COOH + acid chloride->
    ether (benzene-O-R)
  10. HO-benzene-COOH --> ether (benzene-O-R)
    acid chloride
  11. Oxidation of phenols
    HO-benzene-OH (1,4) + 2AgBr -> 3,6-oxohexa-1,4-diene
  12. HO-benzene-OH + 2AgBr ->
    3,6-oxohexa-1,4-diene

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