Benzene Reaction

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Author:
enger91
ID:
85289
Filename:
Benzene Reaction
Updated:
2011-05-11 19:48:13
Tags:
benzene organic chemistry
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Description:
University of MN Twin Cities, CHEM 2302
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  1. nitrobenzene + Sn, conc HCl, heat->
    aniline
  2. nitrobenzene --> aniline
    Sn, conc HCl, heat
  3. aniline + 1)5% HCl, 0C 2)NaNO2 (aq), 0C->
    benzene-N2Cl
  4. aniline --> benzene-N2Cl
    • 1)5% HCl, 0C
    • 2)NaNO2 (aq), 0C
  5. benzene + CuR (aq) 0C->
    benzene-R
  6. benzene --> benzene-R
    CuR (aq) 0C
  7. benzene + R-Cl, anAlCl3, heat->
    benzene-R
  8. benzene --> benzene-R
    R-Cl, anAlCl3, heat
  9. benzene-N2Cl + H2O, heat->
    phenol
  10. benzene --> phenol
    H2O, heat
  11. toulene + NBS, warm->
    phenylbromide (benzene-CH2Br)
  12. toulene --> phenylbromide (benzene-CH2Br)
    NBS, warm
  13. benzene-CH2Br + NaOH->
    phenylalcohol (benzene-CH2OH)
  14. benzene-CH2Br --> benzene-Ch2OH
    NaOH
  15. benzene-C=O-H + NH2NH2, OH-, heat->
    toulene
  16. benzene --> toulene
    NH2NH2, OH-, heat
  17. toulene + KMnO4, heat->
    benzylic acid (benzene-COOH)
  18. toulene --> benylic acid
    KMnO4, heat
  19. benzene ketone + Zn, conc HCl, heat->
    alkylbenzene
  20. benzene ketone --> alkylbenzene
    Zn, conc HCl, heat
  21. aniline + Cl-ketone, anAlCl3, heat->
    benzene-NH-ketone (acetanilide)
  22. aniline --> benzene-NH-ketone (acetanilide)
    Cl-ketone, an AlCl3, heat
  23. benzene-O- + CO2, pressure, H3O+->
    salicylic acid (1,2 HO-benzene-COOH)
  24. benzene-O- --> salicylic acid
    CO2, pressure, H3O+

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