Synthesis of Ketones

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Author:
enger91
ID:
85310
Filename:
Synthesis of Ketones
Updated:
2011-05-11 20:49:30
Tags:
keytones organic chemistry
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University of MN Twin Cities, CHEM 2302
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  1. Oxidation: secondary alcohol --> ketone
    (4 answers)
    • PCC
    • DMSO, COCl2
    • chromic acid (Na7Cr2O7, conc H2SO4)
    • conc HNO3
  2. secondary alcohol + PCC->
    ketone
  3. secondary alcohol + DMSO, COCl2->
    ketone
  4. secondary alcohol + chromic acid->
    ketone
  5. secondary alcohol + conc HNO3->
    ketone
  6. oxymercuration
    terminal alkyne or internal symmetrical alkyne + HgSO4, H2SO4, H2O-> ketone
  7. terminal alkyne or internal symmetrical alkyne + HgSO4, H2SO4, H2O->
    ketone
  8. terminal alkyne or internal symmetrical alkyne --> ketone
    HgSO4, H2SO4, H2O
  9. Hydroboration
    internal symmetrical alkyne + BH, H2O2, H2O, THF, OH--> ketone
  10. internal symmetrical alkyne + BH, H2O2, H2O, THF, OH-->
    ketone
  11. internal symmetrical alkyne --> ketone
    BH, H2O2, H2O, THF, OH-
  12. Ozonalysis
    internal branched alkene + O3, (CH3)2S-> ketone
  13. internal branched alkene + O3, (CH3)2S->
    ketone
  14. internal branched alkene --> ketone
    O3, (CH3)2S
  15. FC acylation
    benzene + acid chloride, anAlCl3, heat-> ketone
  16. benzene + acid chloride, anAlCl3, heat->
    ketone
  17. benzene --> ketone
    acid chloride, anAlCl3, heat
  18. acid chloride + (R)2CuLi->
    ketone
  19. acid chloride --> ketone
    (R)2CuLi
  20. nitrile + R-MgBr, H3O+->
    ketone
  21. nitrile --> ketone
    R-MgBr, H3O+

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