Reactions of Amines

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Author:
enger91
ID:
85457
Filename:
Reactions of Amines
Updated:
2011-05-12 13:14:29
Tags:
amines organic chemistry
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Description:
Universit of MN Twin Cities, CHEM 2302
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  1. R-NH2 (primary) + HCl, NaNO2, 0C->
    R-N+_=N
  2. R-NH2 (primary) --> R-N+_=N
    HCl, NaNO2, 0C
  3. HN-(R)2 (secondary) + N+=O->
    (R)2-NH+-N=O -> (R)2-N-N=O
  4. Hofmann's Elimination
    amine + exhaustive methylation-> Ag2O, H2O-> alkene (least substituted alkene)
  5. amine + 3CH3Br ->
    R-N-(CH3)3
  6. amine --> R-N-(CH3)3
    3CH3Br
  7. R-N-(CH3)3 + Ag2O, H2O->
    alkene (least substituted) + N-(CH3)3
  8. R-N-(CH3)3 --> alkene (least substituted) + N-(CH3)3
    Ag2O, H2O

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